- Sat May 28, 2016 1:07 am
#58575
Unleaded petrol DOES NOT colour spark plugs!
Never has, never will!
Internationally, leaded petrol contained up to .45g of tetra-alkyl lead per litre, though typically the levels was between .2 and .3g per litre. As well as increasing the petrol’s Octane rating, and acting as a valve seat protector, it also acted as a catalysis that burnt off carbon residues from spark plugs and helped to keep them clean. Along with the ‘lead’ were organic chlorides and bromides which further prevented excess fouling of Plugs and lead oxide deposits on piston crowns. None of these ‘scavengers’ are present in unleaded petrol.
The typical density of unleaded ‘Super’ petrol world wide is 0.750 Kg per Litre, compared to 0.735 Kg per L for leaded petrol. The higher density of unleaded petrol provides greater energy content per litre, but requires a slightly LEANER air-fuel ratio to maintain the correct chemical balance during the combustion process. In the real world this equates to a 1-2% change.
In use, the surface of Spark plugs is slowly coated with amorphous carbon, this is more so when the plug temp is below 200c, or the mixture is too rich. If it remains on the plug for periods of time, it is gradually converted into graphite; a good conductor or electricity, and also a ready absorber of water vapours. Such plugs will slowly build up increasing layers of carbon fouling, frequently wet in appearance, though not always, and are highly prone to misfiring issues. At plug temps between 200-400c, the fouling no longer accumulates, but neither does it dissipate. With out Lead in Petrol you need plug temps of between 400-500c to start to see this residue ‘burn off’ and keep the insulator clean.
The removal of Lead oxide, corrosive scavengers, and Lead from petrol has also removed the ‘self cleaning’ properties from petrol. No longer are there the coloured shades of yellow-orange-brown that once used to build up as a glaze on the central porcelain, the former generally accepted indication of ‘optimal’ air-fuel mixture. Which it never was either, it simply indicated optimal Plug operating temps!